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Water as an oxygen source: Synthesis, characterization, and reactivity studies of a mononuclear nonheme manganese(IV) oxo complex

Title
Water as an oxygen source: Synthesis, characterization, and reactivity studies of a mononuclear nonheme manganese(IV) oxo complex
Authors
Sawant S.C.Wu X.Cho J.Cho K.-B.Kim S.H.Seo M.S.Lee Y.-M.Kubo M.Ogura T.Shaik S.Nam W.
Ewha Authors
남원우서미숙조재흥이용민
SCOPUS Author ID
남원우scopus; 이용민scopusscopus
Issue Date
2010
Journal Title
Angewandte Chemie - International Edition
ISSN
1433-7851JCR Link
Citation
vol. 49, no. 44, pp. 8190 - 8194
Indexed
SCI; SCIE; SCOPUS WOS scopus
Abstract
The source of the problem: Experiments with isotopically labeled water can be used to unambiguously assign the source of oxygen in a nonheme manganese(IV) oxo complex. The complex, which was generated using water as an oxygen source and cerium(IV) as an oxidant (see picture), shows reactivities in the activation of C-H bonds of alkyl-functionalized aromatic molecules and the oxidation of aromatic substrates (sub) and benzyl alcohol. © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
DOI
10.1002/anie.201000819
Appears in Collections:
자연과학대학 > 화학·나노과학전공 > Journal papers
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