Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 류재상 | * |
dc.date.accessioned | 2016-08-28T12:08:41Z | - |
dc.date.available | 2016-08-28T12:08:41Z | - |
dc.date.issued | 2010 | * |
dc.identifier.issn | 0039-7881 | * |
dc.identifier.other | OAK-6907 | * |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/221049 | - |
dc.description.abstract | A novel, mild, and chemoselective method was developed for the preparation of gem-diacetates from aldehydes and acetic anhydride in the presence of titanium(IV) fluoride (1-5 mol%) under solvent-free conditions at room temperature. The reaction showed a high chemoselectivity toward aldehydes in the presence of ketones. Moreover, titanium(IV) fluoride also catalyzed the deprotection of gem-diacetates to the corresponding aldehydes in water. This efficient and simple method has several benefits, including the use of an inexpensive catalyst, solvent-free conditions, mild reaction temperatures, and high yields, which make it both cost-effective and environmentally friendly. © Georg Thieme Verlag Stuttgart. | * |
dc.language | English | * |
dc.title | Mild and chemoselective synthesis and deprotection of geminal diacetates catalyzed by titanium(IV) halides | * |
dc.type | Article | * |
dc.relation.issue | 16 | * |
dc.relation.index | SCI | * |
dc.relation.index | SCIE | * |
dc.relation.index | SCOPUS | * |
dc.relation.startpage | 2713 | * |
dc.relation.lastpage | 2720 | * |
dc.relation.journaltitle | Synthesis | * |
dc.identifier.doi | 10.1055/s-0029-1218849 | * |
dc.identifier.wosid | WOS:000282105800005 | * |
dc.identifier.scopusid | 2-s2.0-77955385664 | * |
dc.author.google | Jung M. | * |
dc.author.google | Yoon J. | * |
dc.author.google | Kim H.S. | * |
dc.author.google | Ryu J.-S. | * |
dc.contributor.scopusid | 류재상(36081118200) | * |
dc.date.modifydate | 20231120165709 | * |