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Formic acid acting as an efficient oxygen scavenger in four-electron reduction of oxygen catalyzed by a heterodinuclear iridium-ruthenium complex in water

Title
Formic acid acting as an efficient oxygen scavenger in four-electron reduction of oxygen catalyzed by a heterodinuclear iridium-ruthenium complex in water
Authors
Fukuzumi S.Kobayashi T.Suenobu T.
Ewha Authors
Shunichi Fukuzumi
SCOPUS Author ID
Shunichi Fukuzumiscopus
Issue Date
2010
Journal Title
Journal of the American Chemical Society
ISSN
0002-7863JCR Link
Citation
vol. 132, no. 34, pp. 11866 - 11867
Indexed
SCI; SCIE; SCOPUS WOS scopus
Abstract
A heterodinuclear iridium-ruthenium complex [IrIII(Cp*) (H2O)(bpm)RuII(bpy)2](SO4) 2 (Cp* = φ5-pentamethyl-cyclopentadienyl, bpm = 2,2′-bipyrimidine, bpy = 2,2′-bipyridine) acts as an effective catalyst for removal of dissolved O2 by the four-electron reduction of O2 with formic acid in water at an ambient temperature. © 2010 American Chemical Society.
DOI
10.1021/ja104486h
Appears in Collections:
자연과학대학 > 화학·나노과학전공 > Journal papers
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