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Mononuclear copper complex-catalyzed four-electron reduction of oxygen

Title
Mononuclear copper complex-catalyzed four-electron reduction of oxygen
Authors
Fukuzumi S.Kotani H.Lucas H.R.Doi K.Suenobu T.Peterson R.L.Karlin K.D.
Ewha Authors
Shunichi FukuzumiKenneth D. Karlin
SCOPUS Author ID
Shunichi Fukuzumiscopus
Issue Date
2010
Journal Title
Journal of the American Chemical Society
ISSN
0002-7863JCR Link
Citation
vol. 132, no. 20, pp. 6874 - 6875
Indexed
SCI; SCIE; SCOPUS WOS scopus
Abstract
A mononuclear CuII complex acts as an efficient catalyst for four-electron reduction of O2 to H2O. Its reduction by a ferrocene derivative (Fc*) and reaction with O2 leads to the formation of a peroxodicopper(II) complex; this is subsequently reduced by Fc*in the presence of protons to regenerate the CuII complex. © 2010 American Chemical Society.
DOI
10.1021/ja100538x
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자연과학대학 > 화학·나노과학전공 > Journal papers
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