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A biomimetic ferric hydroperoxo porphyrin intermediate

Title
A biomimetic ferric hydroperoxo porphyrin intermediate
Authors
De Visser S.P.Valentine J.S.Nam W.
Ewha Authors
남원우Joan S. Valentine
SCOPUS Author ID
남원우scopus; Joan S. Valentinescopus
Issue Date
2010
Journal Title
Angewandte Chemie - International Edition
ISSN
1433-7851JCR Link
Citation
vol. 49, no. 12, pp. 2099 - 2101
Indexed
SCI; SCIE; SCOPUS WOS scopus
Abstract
"Chemical Equation Presented" OOH, my! The protonation of a side-on high-spin ferric peroxo species yields the corresponding end-on low-spin ferric hydroperoxo intermediate (see picture), which is a precursor of Compound I and has been frequently proposed as a reactive species in heme enzymes. This ferric hydroperoxo complex can be used to study reactivities of similar species in substrate oxygenation and hydroperoxide O-O bond cleavage reactions. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA.
DOI
10.1002/anie.200906736
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자연과학대학 > 화학·나노과학전공 > Journal papers
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