Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 김성진 | * |
dc.contributor.author | 김영미 | * |
dc.date.accessioned | 2016-08-28T12:08:54Z | - |
dc.date.available | 2016-08-28T12:08:54Z | - |
dc.date.issued | 2010 | * |
dc.identifier.issn | 0277-5387 | * |
dc.identifier.other | OAK-6331 | * |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/220585 | - |
dc.description.abstract | Six new structures of Cd(II) complexes containing Hdpa ligands have been determined. With chloride and bromide, Cd(II) ions produce halide-bridged dinuclear units 1 and 2 while CdI2 produces mononuclear unit 3 without halide-bridging. Cd(II) ions produce mono-Hdpa complex 4 with chelating benzoate, di-Hdpa complex 5 with coordinating NO3 - anion, and tri-Hdpa complexes 6 and 7 with non-coordinating ClO4 - and BF4 - anions. One-, two-, or three-dimensional structures of Cd(II)-Hdpa complexes can be produced by hydrogen bonding interactions and π-π interactions. The compounds 4, 5, and 6 catalyzed efficiently the transesterification of a variety of esters with methanol, while 1, 2, 3 and 7 have displayed a very slow conversion. The transesterification reactivity shown by the catalyst 6 is very efficient and the best among the compounds 1-7. In addition, all compounds 1-7 and ligand (Hdpa) have shown the similar luminescent properties at λmax = 352 nm which suggest that their emissions seem to be attributed to the π-π* intraligand fluorescence. © 2009 Elsevier Ltd. All rights reserved. | * |
dc.language | English | * |
dc.title | Construction of Cd(II) compounds with a chelating ligand 2,2′-dipyridiylamine (Hdpa): Anion effect, catalytic activities and luminescence | * |
dc.type | Article | * |
dc.relation.issue | 2 | * |
dc.relation.volume | 29 | * |
dc.relation.index | SCI | * |
dc.relation.index | SCIE | * |
dc.relation.index | SCOPUS | * |
dc.relation.startpage | 773 | * |
dc.relation.lastpage | 786 | * |
dc.relation.journaltitle | Polyhedron | * |
dc.identifier.doi | 10.1016/j.poly.2009.10.024 | * |
dc.identifier.wosid | WOS:000275020700015 | * |
dc.identifier.scopusid | 2-s2.0-73649097268 | * |
dc.author.google | Park B.K. | * |
dc.author.google | Eom G.H. | * |
dc.author.google | Kim S.H. | * |
dc.author.google | Kwak H. | * |
dc.author.google | Yoo S.M. | * |
dc.author.google | Lee Y.J. | * |
dc.author.google | Kim C. | * |
dc.author.google | Kim S.-J. | * |
dc.author.google | Kim Y. | * |
dc.contributor.scopusid | 김성진(56812714700) | * |
dc.contributor.scopusid | 김영미(57207443602) | * |
dc.date.modifydate | 20240301081003 | * |