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Novel chains constructed from heterotrinuclear units and 1,2-bis(4-pyridyl)ethane formulated as [M2M′(O2CPh)6](bpa) (M = Co, Zn, M′ = Co, Cd): Their catalytic activity

Title
Novel chains constructed from heterotrinuclear units and 1,2-bis(4-pyridyl)ethane formulated as [M2M′(O2CPh)6](bpa) (M = Co, Zn, M′ = Co, Cd): Their catalytic activity
Authors
Lee Y.M.Song Y.J.Poong J.I.Kim S.H.Koo H.G.Lee J.A.Kim C.Kim S.-J.Kim Y.
Ewha Authors
김성진김영미
SCOPUS Author ID
김성진scopus; 김영미scopus
Issue Date
2010
Journal Title
Inorganic Chemistry Communications
ISSN
1387-7003JCR Link
Citation
vol. 13, no. 1, pp. 101 - 104
Indexed
SCI; SCIE; SCOPUS WOS scopus
Abstract
Three novel heterometallic complexes containing two bridging ligands bpa and benzoate, formulated as [M2M′(O2CC6H5]n(bpa)n (bpa = 1,2-bis(4-pyridyl)ethane, M2M′ = Zn2Co (1), Zn2Cd (2), and Co2Cd (3)), have been synthesized. All three compounds show one-dimensional structures containing linear heteronuclear coordination units linked by bridging bpa ligands. Reactivity study of the compounds 1-3 for the transesterification of a variety of esters has shown that they are very efficient and 2 is the best among them. © 2009 Elsevier B.V. All rights reserved.
DOI
10.1016/j.inoche.2009.10.028
Appears in Collections:
자연과학대학 > 화학·나노과학전공 > Journal papers
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