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Synthesis and crystal structure of nickel(II) complexes with bis(5-methyl-2-thiophenemethyl)(2-pyridylmethyl)amine

Title
Synthesis and crystal structure of nickel(II) complexes with bis(5-methyl-2-thiophenemethyl)(2-pyridylmethyl)amine
Authors
Cho J.Lee Y.-M.Kim S.Y.Nam W.
Ewha Authors
남원우조재흥이용민
SCOPUS Author ID
남원우scopus; 이용민scopusscopus
Issue Date
2010
Journal Title
Polyhedron
ISSN
0277-5387JCR Link
Citation
vol. 29, no. 1, pp. 446 - 450
Indexed
SCI; SCIE; SCOPUS WOS scopus
Abstract
A series of nickel(II) complexes having the (Me-Tp)2PMA ligand ((Me-Tp)2PMA = bis(5-methyl-2-thiophenemethyl)(2-pyridylmethyl)amine) with nitrates (1), chlorides (2), and perchlorates (3) as anions were synthesized and isolated. All these complexes were successfully characterized by physicochemical methods including X-ray crystallographic analysis. In complex 1, the ligand binds in a bidentate N2 fashion, whereas in the cases of 2 and 3 the ligand binds in the tridentate N2S form. The coordination geometry around the nickel(II) atoms in these complexes is distorted octahedral. © 2009 Elsevier Ltd. All rights reserved.
DOI
10.1016/j.poly.2009.06.071
Appears in Collections:
자연과학대학 > 화학·나노과학전공 > Journal papers
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