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Tetra-μ-benzoato-bis-{[4-(pyrrolidin-1-yl)pyridine]zinc(II)}

Title
Tetra-μ-benzoato-bis-{[4-(pyrrolidin-1-yl)pyridine]zinc(II)}
Authors
Yu S.M.Koo K.Kim P.-G.Kim C.Kim Y.
Ewha Authors
김영미
SCOPUS Author ID
김영미scopus
Issue Date
2010
Journal Title
Acta Crystallographica Section E: Structure Reports Online
ISSN
1600-5368JCR Link
Citation
vol. 66, no. 1, pp. m61 - m62
Indexed
SCOPUS WOS scopus
Abstract
The central part of the title centrosymmetric dinuclear complex, [Zn 2(C7H5O2)4(C 9H12N2)2], has a paddle-wheel conformation with four benzoate ligands bridging two symmetry-related Zn II ions. The distorted square-pyramidal coordination environment around the ZnII ion is completed by an N atom from a 4-(pyrrolidin-1-yl)pyridine ligand. The Zn⋯Zn separation of 2.9826 (12) Å does not represent a formal direct metal-metal bond. The ZnII ion is displaced by 0.381 (1) Å from the mean plane of the four basal O atoms. Two of the C atoms of the pyrrolidine ring are disordered over two sites with refined occupancies of 0.53 (2) and 0.47 (2).
DOI
10.1107/S1600536809052714
Appears in Collections:
자연과학대학 > 화학·나노과학전공 > Journal papers
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