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Mesolamellar phases containing [Fe(CN)6]3- anion

Title
Mesolamellar phases containing [Fe(CN)6]3- anion
Authors
Vien V.Kim S.-J.
Ewha Authors
김성진
SCOPUS Author ID
김성진scopus
Issue Date
2010
Journal Title
Journal of Materials Science
ISSN
0022-2461JCR Link
Citation
vol. 45, no. 2, pp. 552 - 556
Indexed
SCI; SCIE; SCOPUS WOS scopus
Abstract
The mesostructured lamellar phases with the general formula [C n H2n+1N(CH3)3]3[Fe(CN)6] (n = 14, 16, 18) were prepared by ion-exchange/precipitation reaction of alkyltrimethylammonium surfactants and K3[Fe(CN)6] complex in aqueous medium. The phases were characterized using powder X-ray diffraction, high-resolution transmission electron microscopy, IR spectroscopy, thermogravimetric, and differential scanning calorimetry means. The results obtained all support a proposed model of crystal structure for these materials, in which the layers are constructed by monolayer of the discrete complex molecules, and the surfactants tails of opposite head groups deeply penetrate and arrange with a tilt angle of 63°. © 2009 Springer Science+Business Media, LLC.
DOI
10.1007/s10853-009-3974-x
Appears in Collections:
자연과학대학 > 화학·나노과학전공 > Journal papers
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