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Structural characterization and remarkable axial ligand effect on the nucleophilic reactivity of a nonheme manganese(III)-peroxo complex

Title
Structural characterization and remarkable axial ligand effect on the nucleophilic reactivity of a nonheme manganese(III)-peroxo complex
Authors
Annaraj J.Cho J.Lee Y.-M.Kim S.Y.Latifi R.De Visser S.P.Nam W.
Ewha Authors
남원우조재흥이용민
SCOPUS Author ID
남원우scopus; 이용민scopusscopus
Issue Date
2009
Journal Title
Angewandte Chemie - International Edition
ISSN
1433-7851JCR Link
Citation
vol. 48, no. 23, pp. 4150 - 4153
Indexed
SCI; SCIE; SCOPUS WOS scopus
Abstract
The dark side of the Mn: A manganese(III) complex bearing a 13-membered macrocyclic ligand (1, see picture) binds a peroxo ligand in a side-on η2 fashion. The reactivity of 1 is influenced by the introduction of anionic ligands trans to the peroxo group. Electronic and structural changes upon trans-ligand binding explain the increased nucleophilicity of the resulting complexes 1-X. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.
DOI
10.1002/anie.200900118
Appears in Collections:
자연과학대학 > 화학·나노과학전공 > Journal papers
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