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Water as an oxygen source in the generation of mononuclear nonheme iron(IV) oxo complexes

Title
Water as an oxygen source in the generation of mononuclear nonheme iron(IV) oxo complexes
Authors
Lee Y.-M.Dhuri S.N.Sawant S.C.Cho J.Kubo M.Ogura T.Fukuzumi S.Nam W.
Ewha Authors
남원우조재흥Shunichi Fukuzumi이용민
SCOPUS Author ID
남원우scopus; Shunichi Fukuzumiscopus; 이용민scopusscopus
Issue Date
2009
Journal Title
Angewandte Chemie - International Edition
ISSN
1433-7851JCR Link
Citation
vol. 48, no. 10, pp. 1803 - 1806
Indexed
SCI; SCIE; SCOPUS WOS scopus
Abstract
Give me an "O"! Mononuclear nonheme iron(IV) oxo complexes have been generated using water as an oxygen source and cerium(IV) as an oxidant. The high-yield oxygenation of organic substrates in this system (see picture, Fe green, O red, N blue, C gray) is catalyzed by iron(II) complexes. The source of oxygen in the iron(IV) oxo complexes and the oxygenated products has been assigned unambiguously by isotopic labeling experiments. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.
DOI
10.1002/anie.200805670
Appears in Collections:
자연과학대학 > 화학·나노과학전공 > Journal papers
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