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Reactive intermediates in oxygenation reactions with mononuclear nonheme iron catalysts

Title
Reactive intermediates in oxygenation reactions with mononuclear nonheme iron catalysts
Authors
Yoon J.Wilson S.A.Jang Y.K.Seo M.S.Nehru K.Hedman B.Hodgson K.O.Bill E.Solomon E.I.Nam W.
Ewha Authors
남원우서미숙
SCOPUS Author ID
남원우scopus
Issue Date
2009
Journal Title
Angewandte Chemie - International Edition
ISSN
1433-7851JCR Link
Citation
vol. 48, no. 7, pp. 1257 - 1260
Indexed
SCI; SCIE; SCOPUS WOS scopus
Abstract
An advanced intermediate: A nonheme iron(IV) oxo complex [Fe IV(O)(bqen)(L)] n+ (bqen=N,N r-dimethyl-N,N r -bis(8-quinolyl)ethane-1,2-diamine, L=CH 3CN or CF 3SO 3-) activates the C - H bonds of alkanes and alcohols by a hydrogen-atom abstraction mechanism. The catalytic oxidation of these species is proposed to occur through a nonheme iron(V) oxo species, with a high reactivity in oxidation reactions (see picture). © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.
DOI
10.1002/anie.200802672
Appears in Collections:
자연과학대학 > 화학·나노과학전공 > Journal papers
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