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An iron(II) complex with a N3S2 thioether ligand in the generation of an iron(IV)-oxo complex and its reactivity in olefin epoxidation

Title
An iron(II) complex with a N3S2 thioether ligand in the generation of an iron(IV)-oxo complex and its reactivity in olefin epoxidation
Authors
Annaraj J.Kim S.Seo M.S.Lee Y.-M.Kim Y.Kim S.-J.Choi Y.S.Jang H.G.Nam W.
Ewha Authors
김성진남원우김영미서미숙이용민
SCOPUS Author ID
김성진scopus; 남원우scopus; 김영미scopus; 이용민scopusscopus
Issue Date
2009
Journal Title
Inorganica Chimica Acta
ISSN
0020-1693JCR Link
Citation
vol. 362, no. 3, pp. 1031 - 1034
Indexed
SCI; SCIE; SCOPUS WOS scopus
Abstract
A new iron(II) complex bearing an N3S2 thioether ligand was synthesized and characterized with various spectroscopic techniques and X-ray crystallography. A mononuclear nonheme iron(IV)-oxo intermediate was generated in the reaction of the iron(II) complex with various terminal oxidants. The iron(IV)-oxo species show a capability of epoxidizing olefins, and the olefin epoxidation occurs via an electrophilic oxidation mechanism. © 2008 Elsevier B.V. All rights reserved.
DOI
10.1016/j.ica.2008.04.018
Appears in Collections:
자연과학대학 > 화학·나노과학전공 > Journal papers
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