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Experiment and theory reveal the fundamental difference between two-state and single-state reactivity patterns in nonheme FeIV=O versus Ru IV=O oxidants

Title
Experiment and theory reveal the fundamental difference between two-state and single-state reactivity patterns in nonheme FeIV=O versus Ru IV=O oxidants
Authors
Dhuri S.N.Mi S.S.Lee Y.-M.Hirao H.Wang Y.Nam W.Shaik S.
Ewha Authors
남원우이용민서미숙
SCOPUS Author ID
남원우scopus; 이용민scopusscopus
Issue Date
2008
Journal Title
Angewandte Chemie - International Edition
ISSN
1433-7851JCR Link
Citation
vol. 47, no. 18, pp. 3356 - 3359
Indexed
SCI; SCIE; SCOPUS WOS scopus
Abstract
(Chemical Equation Presented) Two-state reactivity involving close triplet ground and quintet excited states is responsible for the opposite reactivity trends of FeIV oxo complexes in O-transfer and H-abstraction reactions in dependence on the electron richness of the axial ligand X (see picture), as shown by comparison with RuIV analogues, in which both reactivities are solely governed by the electrophilicity of the complex because the quintet state is inaccessible. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
DOI
10.1002/anie.200705880
Appears in Collections:
자연과학대학 > 화학·나노과학전공 > Journal papers
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