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Fundamental electron-transfer properties of non-heme oxoiron(IV) complexes

Title
Fundamental electron-transfer properties of non-heme oxoiron(IV) complexes
Authors
Lee Y.-M.Kotani H.Suenobu T.Nam W.Fukuzumi S.
Ewha Authors
남원우이용민Shunichi Fukuzumi
SCOPUS Author ID
남원우scopus; Shunichi Fukuzumiscopus; 이용민scopusscopus
Issue Date
2008
Journal Title
Journal of the American Chemical Society
ISSN
0002-7863JCR Link
Citation
vol. 130, no. 2, pp. 434 - 435
Indexed
SCI; SCIE; SCOPUS WOS scopus
Abstract
Electron-transfer kinetics for the reduction of non-heme oxoiron(IV) complexes by a series of ferrocene derivatives were examined in deaerated acetonitrile, and the resulting data were evaluated in light of the Marcus theory of electron transfer to determine the reorganization energies of electron transfer and the one-electron reduction potentials of non-heme oxoiron(IV) complexes. The electron-transfer properties of non-heme oxoiron(IV) complexes are featured by the larger reorganization energies of electron transfer and the lower one-electron reduction potentials as compared with those of heme oxoiron(IV) complexes. Copyright © 2008 American Chemical Society.
DOI
10.1021/ja077994e
Appears in Collections:
자연과학대학 > 화학·나노과학전공 > Journal papers
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