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[Mn(tmc)(O2)]+: A side-on peroxido manganese(III) complex bearing a non-heme ligand

Title
[Mn(tmc)(O2)]+: A side-on peroxido manganese(III) complex bearing a non-heme ligand
Authors
Seo M.S.Kim J.Y.Annaraj J.Kim Y.Lee Y.-M.Kim S.-J.Kim J.Nam W.
Ewha Authors
김성진남원우김영미김진흥이용민서미숙
SCOPUS Author ID
김성진scopus; 남원우scopus; 김영미scopus; 김진흥scopus; 이용민scopusscopus
Issue Date
2007
Journal Title
Angewandte Chemie - International Edition
ISSN
1433-7851JCR Link
Citation
vol. 46, no. 3, pp. 377 - 380
Indexed
SCI; SCIE; SCOPUS WOS scopus
Abstract
(Chemical Equation Presented) On the side: The crystal structure of a peroxido MnIII complex bearing a non-heme ligand shows that the peroxide ligand is bound to a manganese ion symmetrically in a side-on η2 fashion. The complex is capable of deformylating aldehydes by a nucleophilic reaction but not capable of oxygenating substrates by an electrophilic reaction. tmc = 1,4,8,11-tetramethyl-1,4,8,11- tetraazacyclotetradecane. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.
DOI
10.1002/anie.200603414
Appears in Collections:
자연과학대학 > 화학·나노과학전공 > Journal papers
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