Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 이종목 | * |
dc.date.accessioned | 2016-08-28T11:08:42Z | - |
dc.date.available | 2016-08-28T11:08:42Z | - |
dc.date.issued | 2004 | * |
dc.identifier.issn | 0253-2964 | * |
dc.identifier.other | OAK-2293 | * |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/219458 | - |
dc.description.abstract | The synthesis of novel group 9 metal complexes containing the S,S′-chelate ligands, Li2S2C2B 10H10 (2a) and LiS(S=PMe2)C2B 10H10 (2b), is described. Two new dinuclear complexes of the type [{(cod)M}2(S,S′-S2C2B 10H10)] (cod = 1,5-cyclooctadiene; M = Rh (3a), or Ir (3b)) were synthesized by the reaction of chloride-bridged dimers [M(μ-Cl)(cod)]2 with one molar equivalent of the corresponding dilithium dithiolato ligand Li2S2C2B 10H10 (2a). X-ray crystal structure analysis of 3a revealed a dinuclear structure in which each (cod)Rh unit is attached to a distinct sulfur atom of a 1,2-dithio-o-carboranyl ligand (2a). Additionally, the electrochemical properties of 3a and 3b were investigated by cyclic voltammetry. In an analogous manner, reaction of the lithium dithiolato ligand LiS(S=PMe2)C2B10H10 (2b) with Cp*CoI2(CO) produced a mononuclear dithiolato complex, [Cp*CoI{(S,S′-S(S=PMe2)C2B10H 10)}] (4), which was characterized by single-crystal X-ray analysis. | * |
dc.language | English | * |
dc.title | Novel group 9 metal complexes containing an S,S′-chelating o-carboranyl ligand system: Synthesis, crystal structures, and electrochemical properties of dinuclear [{(cod)M}2(S,S′-S2C 2B10H10)] (cod = 1,5-cyclooctadiene; M = Rh or Ir) and mononuclear Cp*CoI[S,S′-S(S=PMe2)C 2B10H10] | * |
dc.type | Article | * |
dc.relation.issue | 7 | * |
dc.relation.volume | 25 | * |
dc.relation.index | SCI | * |
dc.relation.index | SCIE | * |
dc.relation.index | SCOPUS | * |
dc.relation.index | KCI | * |
dc.relation.startpage | 1012 | * |
dc.relation.lastpage | 1018 | * |
dc.relation.journaltitle | Bulletin of the Korean Chemical Society | * |
dc.identifier.wosid | WOS:000223135900014 | * |
dc.identifier.scopusid | 2-s2.0-5444229237 | * |
dc.author.google | Lee J.-D. | * |
dc.author.google | Bo Y.K. | * |
dc.author.google | Lee C. | * |
dc.author.google | Lee Y.-J. | * |
dc.author.google | Ko J. | * |
dc.author.google | Sang O.K. | * |
dc.contributor.scopusid | 이종목(55812178500) | * |
dc.date.modifydate | 20240415121732 | * |