Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 이종목 | * |
dc.date.accessioned | 2016-08-28T11:08:32Z | - |
dc.date.available | 2016-08-28T11:08:32Z | - |
dc.date.issued | 2003 | * |
dc.identifier.issn | 0022-328X | * |
dc.identifier.other | OAK-1743 | * |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/219346 | - |
dc.description.abstract | Reaction of the 16-electron dithiolatocobalt, [(η5- Cp*)Co(CabS,S′)] (1) (CabS,S′=1, 2-S2C2B10H10-S,S′), with a ligand L (L=CNtBu, PMe3, PEt3, PHPh2) affords the 18-electron complexes [(η5- Cp*)Co(CabS,S′)(L)] (2) in high yield. The structures of 2 in solution were probed by NMR spectroscopy, and the solid-state structure of the diphenylphosphine derivative was established by single-crystal X-ray diffraction. Cyclic voltammetry of 1 shows that the complex undergoes a quasi-reversible one-electron oxidation and reversible reduction. The voltammetry of the corresponding 18-electron complex 2 was investigated rather extensively in terms of coordination and redox chemistry, in which the influence of the enhanced steric interaction between the bulky Cp* and incoming ligand could be observed. Cyclic voltammograms of alkylidiene or acetylene adducts of dithiolatocobalt complex 1, [(η5-Cp*)Co{η 3-(S,S′, C′)-SC2B10 H10S(C′R2)}] [C′R2=CHSiMe 3 (3a), HC=CPh (3b), (COOMe)C=C(COOMe) (3c)], are also included. © 2003 Elsevier B.V. All rights reserved. | * |
dc.language | English | * |
dc.title | Electrochemical behavior of the Cp*(dithiolato)Co(III) complex [(η5-Cp*)Co(1,2-S2C2 B10H10-S,S′)] and its derivatives: The effect of the ligand on half-sandwich cobalt(III) complexes | * |
dc.type | Article | * |
dc.relation.issue | 1-2 | * |
dc.relation.volume | 688 | * |
dc.relation.index | SCI | * |
dc.relation.index | SCIE | * |
dc.relation.index | SCOPUS | * |
dc.relation.startpage | 236 | * |
dc.relation.lastpage | 245 | * |
dc.relation.journaltitle | Journal of Organometallic Chemistry | * |
dc.identifier.doi | 10.1016/j.jorganchem.2003.09.019 | * |
dc.identifier.wosid | WOS:000186917700032 | * |
dc.identifier.scopusid | 2-s2.0-0242487681 | * |
dc.author.google | Kim B.Y. | * |
dc.author.google | Lee C. | * |
dc.author.google | Chung S.W. | * |
dc.author.google | Lee Y.-J. | * |
dc.author.google | Pak J. | * |
dc.author.google | Ko J. | * |
dc.author.google | Kang S.O. | * |
dc.contributor.scopusid | 이종목(55812178500) | * |
dc.date.modifydate | 20240415121732 | * |