Dimethanoltetrakis[5,10,15,20-tetrakis-(2,6-dichlorophenyl)porphinato] manganese(III) hexacyanooctaselenidorhenate(III) tridecahydrate

Abstract

The crystal structure of the title compound, [Mn(TDC)]4[Re 6Se8(CN)6]·13H2O, contains discrete [Re6Se8(CN)6]4-nd Mn(TDC)+ moieties [TDC is the tetrakis(2,6-dichlorophenyl)-porphinate dianion, C44H20Cl8N4 2-]. The anion as well as two of the cations lie on crystallographic centers of symmetry. Each Mn(TDC)+ cation is octahedral with two axial methanol ligands. The coordinated methanol groups form O-H⋯O hydrogen bonds to solvent water molecules of crystallization in the lattice. © 2003 International Union of Crystallography Printed in Great Britain - all rights reserved.