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Chelation-accelerated sequential decarbonylation of formate and alkoxycarbonylation of aryl halides using a combined Ru and Pd catalyst

Title
Chelation-accelerated sequential decarbonylation of formate and alkoxycarbonylation of aryl halides using a combined Ru and Pd catalyst
Authors
Ko S.Lee C.Choi M.-G.Na Y.Chang S.
Ewha Authors
이종목
SCOPUS Author ID
이종목scopus
Issue Date
2003
Journal Title
Journal of Organic Chemistry
ISSN
0022-3263JCR Link
Citation
vol. 68, no. 4, pp. 1607 - 1610
Indexed
SCI; SCIE; SCOPUS WOS scopus
Abstract
An efficient cooperative catalyst system for the coupling of a wide range of organic electrophiles with chelated formate is reported to afford aryl and alkenyl esters by the simultaneous employment of Ru and Pd catalyst, in which ruthenium first promotes chelation-accelerated decarbonylation of formate to release CO and carbinol that are presumed to be transferred, still chelated to Ru, into Pd catalyst, which catalyzes alkoxycarbonylation of the organic electrophiles.
DOI
10.1021/jo026591o
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자연과학대학 > 화학·나노과학전공 > Journal papers
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