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dc.contributor.author강원-
dc.date.accessioned2016-08-28T11:08:04Z-
dc.date.available2016-08-28T11:08:04Z-
dc.date.issued2002-
dc.identifier.issn1058-725X-
dc.identifier.otherOAK-1170-
dc.identifier.urihttp://dspace.ewha.ac.kr/handle/2015.oak/219050-
dc.description.abstractSingle crystals of new organic metal, (ET)MT)2(BF 4)(THF). were electrochemically grown in an H-type cell. In the X-ray crystal structure, ET and MT donors together form a layer in ac-plane, which is stacking along b-axis alternatively with the layer formed by BF 4 - and THF. Within the mixed-donor layer, MT molecules (stacking along a-axis) and ET molecules (arranged side-by-side) are almost perpendicular each other with their long in-plane molecular axes being along b-axis. ET and MT molecules within a layer are closely connected by short S . . . S interactions (3.226-3.694 Å) and achieve the2D S . . . S network. Band electronic structure calculations on this complex show that it is a 2D metal at r.t. Bands are more dispersive along the a-axis which means that electrical conductivity is possibly better along this direction. However, the Fermi surface nesting which arises in many low dimensional metals, was not found.-
dc.languageEnglish-
dc.titleNew organic metal containing mixed donors: (ET)(MT)2(BF 4)(THF)-
dc.typeConference Paper-
dc.relation.volume380-
dc.relation.indexSCOPUS-
dc.relation.startpage123-
dc.relation.lastpage128-
dc.relation.journaltitleMolecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals-
dc.identifier.doi10.1080/10587250290101450-
dc.identifier.wosidWOS:000177784900017-
dc.identifier.scopusid2-s2.0-11144234262-
dc.author.googleNoh D.-Y.-
dc.author.googleHan S.-W.-
dc.author.googleLee H.-J.-
dc.author.googleJung D.-
dc.author.googleKang W.-
dc.contributor.scopusid강원(7202402145)-
dc.date.modifydate20170601102924-
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