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Control of the stoichiometry in host-guest complexation by redox chemistry of guests: Inclusion of methylviologen in cucurbit[8]uril

Title
Control of the stoichiometry in host-guest complexation by redox chemistry of guests: Inclusion of methylviologen in cucurbit[8]uril
Authors
Jeon W.S.Kim H.-J.Lee C.Kim K.
Ewha Authors
이종목
SCOPUS Author ID
이종목scopus
Issue Date
2002
Journal Title
Chemical Communications
ISSN
1359-7345JCR Link
Citation
vol. 8, no. 17, pp. 1828 - 1829
Indexed
SCI; SCIE; SCOPUS WOS scopus
Abstract
The binding stoichiometry of a host-guest complex can be effectively controlled by the redox chemistry of the guest: a 1:1 inclusion complex of methylviologen dication (MV2+) in cucurbit[8]uril (CB[8]) converts completely and reversibly to a 2:1 inclusion complex of cation radical (MV+·) in CB[8] upon the reduction of the guest.
DOI
10.1039/b202082c
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자연과학대학 > 화학·나노과학전공 > Journal papers
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