Full metadata record
DC Field | Value | Language |
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dc.contributor.author | 박준우 | - |
dc.date.accessioned | 2016-08-28T11:08:58Z | - |
dc.date.available | 2016-08-28T11:08:58Z | - |
dc.date.issued | 2002 | - |
dc.identifier.issn | 1089-5647 | - |
dc.identifier.other | OAK-1046 | - |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/218989 | - |
dc.description.abstract | A monofunctional derivative of β-cyclodextrin (β-CD) containing a 2-sulfonato-6-naphthyl group at the primary face (1: β-CD-NS) was prepared. The concentration dependences of fluorescence, circular dichroism (c.d.), and NMR spectra of 1 have been investigated and compared with the spectral changes associated with complexation of 6-methoxy-2-naphthalenesulfonate (MNSS) with β-CD. When the concentration of 1 was increased, the following were observed: the enhancement of the concentration-normalized fluorescence intensity; an increase in molar ellipticities of the negative band around 280 nm; a more pronounced exciton coupling band around 230 nm in c.d. spectra; and an upfield shift of NMR signals from aromatic protons. The concentration dependent fluorescent intensity and molar ellipticity data fitted well to the monomerdimer equilibrium of 1 with the dimerization constant of 9700 ± 2500 M -1. The dimerization constant is much larger than the association constants of MNSS with β-CD (510 ± 40 M -1) and 1 with β-CD (430 ± 50 M -1). The naphthyl groups in the dimer do not show an excimer band in fluorescence spectra but exhibit exciton coupling bands around 230 and 330 nm. These indicate that 1 forms a head-to-head type dimer, which is stabilized by mutual inclusion of the 2-sulfonato-6-naphthyl moieties deeply into β-CD cavities of counter molecules. The naphthyl moiety of the monomer of 1 is in a similar environment to that in a 1/noctyl sulfate complex and appears to cap the primary face of β-CD loosely. Compared to the c.d. spectrum of the MNSS/β-CD complex, the spectrum of the 1/β-CD complex is similar in shape, but the rotational strengths of the c.d. bands are much greater. | - |
dc.language | English | - |
dc.title | Facile dimerization and circular dichroism characteristics of 6-O-(2-sulfonato-6-naphthyl)-β-cyclodextrin | - |
dc.type | Article | - |
dc.relation.issue | 20 | - |
dc.relation.volume | 106 | - |
dc.relation.index | SCOPUS | - |
dc.relation.startpage | 5177 | - |
dc.relation.lastpage | 5183 | - |
dc.relation.journaltitle | Journal of Physical Chemistry B | - |
dc.identifier.doi | 10.1021/jp014191j | - |
dc.identifier.wosid | WOS:000175639300007 | - |
dc.identifier.scopusid | 2-s2.0-0037162161 | - |
dc.author.google | Park J.W. | - |
dc.author.google | Song H.E. | - |
dc.author.google | Lee S.Y. | - |
dc.contributor.scopusid | 박준우(35332923800) | - |
dc.date.modifydate | 20220119160750 | - |