Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 고수영 | - |
dc.date.accessioned | 2016-08-28T11:08:57Z | - |
dc.date.available | 2016-08-28T11:08:57Z | - |
dc.date.issued | 2002 | - |
dc.identifier.issn | 0022-3263 | - |
dc.identifier.other | OAK-1020 | - |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/218975 | - |
dc.description.abstract | Mitsunobu reactions of syn-2,3-dihydroxy esters exhibit a complete regioselection for the β-hydroxyl group. Benzoylation, azidation, and tosylation have been performed under these conditions. β-Functionalizations of syn-2,3-dihydroxy esters are uncommon, and the Mitsunobu reactions are complementary to other diol chemistries in the regioselection. In addition, the configurational inversion accompanying the Mitsunobu protocol offers a means for diastereochemical diversity, as exemplified by a synthesis of statine and its anti diastereomer. These findings will further expand the synthetic utilities of the Sharpless AD process. | - |
dc.language | English | - |
dc.title | Unusual regioselection in the Mitsunobu reactions of syn-2,3-dihydroxy esters: Synthesis of statine and its diastereomer | - |
dc.type | Article | - |
dc.relation.issue | 8 | - |
dc.relation.volume | 67 | - |
dc.relation.index | SCI | - |
dc.relation.index | SCIE | - |
dc.relation.index | SCOPUS | - |
dc.relation.startpage | 2689 | - |
dc.relation.lastpage | 2691 | - |
dc.relation.journaltitle | Journal of Organic Chemistry | - |
dc.identifier.doi | 10.1021/jo015967f | - |
dc.identifier.wosid | WOS:000175169000041 | - |
dc.identifier.scopusid | 2-s2.0-0037134203 | - |
dc.author.google | Ko S.Y. | - |
dc.contributor.scopusid | 고수영(7403325351) | - |
dc.date.modifydate | 20230208103927 | - |