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Methoxy[meso-5,10,15,20-tetrakis-(2,6-difluorophenyl)porphyrinato]-iron(III), [Fe(TDFPP)(OCH3)]
- Title
- Methoxy[meso-5,10,15,20-tetrakis-(2,6-difluorophenyl)porphyrinato]-iron(III), [Fe(TDFPP)(OCH3)]
- Authors
- Kim Y.; Nam W.; Lim M.H.; Jin S.W.; Lough A.J.; Kim S.-J.
- Ewha Authors
- 김성진; 남원우; 김영미
- SCOPUS Author ID
- 김성진; 남원우; 김영미
- Issue Date
- 2001
- Journal Title
- Acta Crystallographica Section C: Crystal Structure Communications
- ISSN
- 0108-2701
- Citation
- Acta Crystallographica Section C: Crystal Structure Communications vol. 57, no. 5, pp. 556 - 557
- Indexed
- SCOPUS
- Document Type
- Article
- Abstract
- The crystal structure of the title compound, [Fe(C44H20F8N4)- (CH3O)], has been determined. The Fe atom lies 0.485 (1) ,Å out of the plane of the four N atoms to which it is coordinated and from the inversion centre at the origin of the unit cell. The methoxy group is axially coordinated to the Fe atom with O-Fe-N angles of 106.3 (2) and 102.4 (2)°, a C-O-Fe angle of 128.3 (5)° and an Fe-O distance of 1.788 (5) Å. Difluorophenyl rings are tilted from the porphyrin (por) plane with torsion angles of -68.1 (6) and 77.7 (5)° across the two Cpor-C-C-Car systems.
- DOI
- 10.1107/S0108270101003006
- Appears in Collections:
- 자연과학대학 > 화학·나노과학전공 > Journal papers
- Files in This Item:
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Methoxy[meso-5,10,15,20-tetrakis-(2,6-difluorophenyl)porphyrinato]-iron(III), [Fe(TDFPP)(OCH3)].pdf(88.09 kB)
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