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Methoxy[meso-5,10,15,20-tetrakis-(2,6-difluorophenyl)porphyrinato]-iron(III), [Fe(TDFPP)(OCH3)]

Title
Methoxy[meso-5,10,15,20-tetrakis-(2,6-difluorophenyl)porphyrinato]-iron(III), [Fe(TDFPP)(OCH3)]
Authors
Kim Y.Nam W.Lim M.H.Jin S.W.Lough A.J.Kim S.-J.
Ewha Authors
김성진남원우김영미
SCOPUS Author ID
김성진scopus; 남원우scopus; 김영미scopus
Issue Date
2001
Journal Title
Acta Crystallographica Section C: Crystal Structure Communications
ISSN
0108-2701JCR Link
Citation
vol. 57, no. 5, pp. 556 - 557
Indexed
SCOPUS WOS scopus
Abstract
The crystal structure of the title compound, [Fe(C44H20F8N4)- (CH3O)], has been determined. The Fe atom lies 0.485 (1) ,Å out of the plane of the four N atoms to which it is coordinated and from the inversion centre at the origin of the unit cell. The methoxy group is axially coordinated to the Fe atom with O-Fe-N angles of 106.3 (2) and 102.4 (2)°, a C-O-Fe angle of 128.3 (5)° and an Fe-O distance of 1.788 (5) Å. Difluorophenyl rings are tilted from the porphyrin (por) plane with torsion angles of -68.1 (6) and 77.7 (5)° across the two Cpor-C-C-Car systems.
DOI
10.1107/S0108270101003006
Appears in Collections:
자연과학대학 > 화학·나노과학전공 > Journal papers
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