Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 엄익환 | - |
dc.contributor.author | 박종윤 | - |
dc.date.accessioned | 2016-08-28T11:08:21Z | - |
dc.date.available | 2016-08-28T11:08:21Z | - |
dc.date.issued | 1999 | - |
dc.identifier.issn | 0040-4039 | - |
dc.identifier.other | OAK-332 | - |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/218583 | - |
dc.description.abstract | Pseudo-first-order rate constants (k(obs)) have been measured spectrophotometrically for aminolyses of dibenzo[1,2]oxathiin-6-oxide. The plot of k(obs) vs amine concentrations exhibits a downward curvature which levels off as the amine concentration increases. Such a downward curvature is proposed as definitive evidence for a stepwise mechanism, which is supported by the microscopic rate constants determined. | - |
dc.language | English | - |
dc.title | Definitive evidence for a stepwise mechanism: A downward curvature in the plot of k(obs) versus amine concentrations in aminolysis reactions of dibenzo[1,2]oxathiin-6-oxide | - |
dc.type | Article | - |
dc.relation.issue | 50 | - |
dc.relation.volume | 40 | - |
dc.relation.index | SCI | - |
dc.relation.index | SCIE | - |
dc.relation.index | SCOPUS | - |
dc.relation.startpage | 8901 | - |
dc.relation.lastpage | 8904 | - |
dc.relation.journaltitle | Tetrahedron Letters | - |
dc.identifier.wosid | WOS:000083827200043 | - |
dc.identifier.scopusid | 2-s2.0-0033544794 | - |
dc.author.google | Um I.-H. | - |
dc.author.google | Lee H.-W. | - |
dc.author.google | Park J.-Y. | - |
dc.contributor.scopusid | 엄익환(7006725706;6506759437) | - |
dc.contributor.scopusid | 박종윤(15036487300) | - |
dc.date.modifydate | 20230411105538 | - |