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Use of 2-methyl-1-phenylpropan-2-yl hydroperoxide (MPPH) as a mechanistic probe for the heterolytic versus homolytic O-O bond cleavage of tert-alkyl hydroperoxide by iron(III) porphyrin complex

Title
Use of 2-methyl-1-phenylpropan-2-yl hydroperoxide (MPPH) as a mechanistic probe for the heterolytic versus homolytic O-O bond cleavage of tert-alkyl hydroperoxide by iron(III) porphyrin complex
Authors
Nam W.Choi H.J.Han H.J.Cho S.H.Lee H.J.Han S.-Y.
Ewha Authors
남원우한소엽
SCOPUS Author ID
남원우scopus; 한소엽scopus
Issue Date
1999
Journal Title
Chemical Communications
ISSN
1359-7345JCR Link
Citation
no. 4, pp. 387 - 388
Indexed
SCI; SCIE; SCOPUS WOS scopus
Abstract
The mechanism of the O-O bond cleavage of tert-alkyl hydroperoxide by iron(III) porphyrin complexes has been studied using 2-methyl-1-phenylpropan-2-yl hydroperoxide (MPPH) as a mechanistic probe; the hydroperoxide O-O bond is cleaved both heterolytically and homolytically and partitioning between the two pathways significantly depends on the reaction conditions such as the pH of the reaction solutions and the nature of porphyrin and axial ligands.
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자연과학대학 > 화학·나노과학전공 > Journal papers
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