View : 27 Download: 0

Synthesis of cyclopenta-fused polycyclic aromatic hydrocarbons utilizing aryl-substituted anilines

Title
Synthesis of cyclopenta-fused polycyclic aromatic hydrocarbons utilizing aryl-substituted anilines
Authors
Choi, YeojinChatterjee, TanmayKim, JunKim, Jun SooCho, Eun Jin
Ewha Authors
김준수
SCOPUS Author ID
김준수scopus
Issue Date
2016
Journal Title
ORGANIC & BIOMOLECULAR CHEMISTRY
ISSN
1477-0520JCR Link1477-0539JCR Link
Citation
vol. 14, no. 28, pp. 6804 - 6810
Publisher
ROYAL SOC CHEMISTRY
Indexed
SCI; SCIE; SCOPUS WOS scopus
Abstract
Cyclopenta-fused polycyclic aromatic hydrocarbons (CP-PAHs), potentially electronically and biologically highly active materials, were synthesized from readily available 2-aryl-substituted anilines. Reactions occur under extremely mild, room temperature conditions using (BuONO)-Bu-t as the sole reagent. The use of a nitrite source generates a reactive diazonium intermediate in situ that then reacts with a tethered polycyclic aromatic moiety by intramolecular aromatic substitution. This protocol could be presented as one of the simplest methods to access CP-PAHs.
DOI
10.1039/c6ob01235c
Appears in Collections:
자연과학대학 > 화학·나노과학전공 > Journal papers
Files in This Item:
There are no files associated with this item.
Export
RIS (EndNote)
XLS (Excel)
XML


qrcode

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.

BROWSE