Photoinduced electron transfer in porous organic salt crystals impregnated with fullerenes

Abstract

Porous organic salt (POS) crystals composed of 9-(4-sulfophenyl)anthracene (SPA) and triphenylmethylamine (TPMA) were impregnated with fullerenes (C-60 and C-70), which were arranged in one dimensional close contact. POS crystals of SPA and TPMA without fullerenes exhibit blue fluorescence due to SPA, whereas the fluorescence was quenched in POS with fullerenes due to electron transfer from the singlet excited state of SPA to fullerenes.