Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 남원우 | * |
dc.contributor.author | 이용민 | * |
dc.contributor.author | 서미숙 | * |
dc.date.accessioned | 2016-08-27T04:08:58Z | - |
dc.date.available | 2016-08-27T04:08:58Z | - |
dc.date.issued | 2015 | * |
dc.identifier.issn | 1433-7851 | * |
dc.identifier.issn | 1521-3773 | * |
dc.identifier.other | OAK-15474 | * |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/217505 | - |
dc.description.abstract | High-spin iron(III)-iodosylarene complexes are highly reactive in the epoxidation of olefins, in which epoxides are formed as the major products with high stereospecificity and enantioselectivity. The reactivity of the iron(III)-iodosylarene intermediates is much greater than that of the corresponding iron(IV)-oxo complex in these reactions. The iron(III)-iodosylarene species-not high-valent iron(IV)-oxo and iron(V)-oxo species-are also shown to be the active oxidants in catalytic olefin epoxidation reactions. The present results are discussed in light of the long-standing controversy on the one oxidant versus multiple oxidants hypothesis in oxidation reactions. | * |
dc.language | English | * |
dc.publisher | WILEY-V C H VERLAG GMBH | * |
dc.subject | bioinorganic chemistry | * |
dc.subject | enzyme models | * |
dc.subject | epoxidation | * |
dc.subject | iron complexes | * |
dc.subject | reaction mechanisms | * |
dc.title | Mononuclear Nonheme Iron(III)-Iodosylarene and High-Valent Iron-Oxo Complexes in Olefin Epoxidation Reactions | * |
dc.type | Article | * |
dc.relation.issue | 40 | * |
dc.relation.volume | 54 | * |
dc.relation.index | SCI | * |
dc.relation.index | SCIE | * |
dc.relation.index | SCOPUS | * |
dc.relation.startpage | 11740 | * |
dc.relation.lastpage | 11744 | * |
dc.relation.journaltitle | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | * |
dc.identifier.doi | 10.1002/anie.201505796 | * |
dc.identifier.wosid | WOS:000363394800024 | * |
dc.identifier.scopusid | 2-s2.0-84942295578 | * |
dc.author.google | Wang, Bin | * |
dc.author.google | Lee, Yong-Min | * |
dc.author.google | Seo, Mi Sook | * |
dc.author.google | Nam, Wonwoo | * |
dc.contributor.scopusid | 남원우(7006569723) | * |
dc.contributor.scopusid | 이용민(36546331100;35233855500;57192113229) | * |
dc.contributor.scopusid | 서미숙(7101805112) | * |
dc.date.modifydate | 20240426135715 | * |