Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 남원우 | * |
dc.contributor.author | 김관묵 | * |
dc.contributor.author | 김진흥 | * |
dc.contributor.author | 서미숙 | * |
dc.date.accessioned | 2016-08-27T02:08:30Z | - |
dc.date.available | 2016-08-27T02:08:30Z | - |
dc.date.issued | 2006 | * |
dc.identifier.issn | 0253-2964 | * |
dc.identifier.other | OAK-3529 | * |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/216022 | - |
dc.description.abstract | A macrocyclic ligand, N,N',N ''-tribenzyl-2,11,20-triaza[3,3,3](2,6)pyridinophane (BAPP), was used to prepare an iron(H) complex as a nonheme model complex, [(BAPP)Fe] 2 (1). X-ray crystallography of a colorless crystal of 1 revealed that BAPP acted as a pentadentate ligand due to geometrical strain for the formation of a six-coordinate iron(II) complex by BAPP. As a result, the iron center revealed a significantly distorted square pyramidal geometry similar to that found in the active site of taurine dioxygenase (tauD). In the reaction of I with PhIO, no intermediate was observed in the UV-visible region of spectrometer at low temperatures. Catalytic oxidations of triphenyl phosphine with PhIO at -40 degrees C revealed that 1 was able to convert triphenyl phosphine to triphenyl phosphine oxide. Thioanisole was also oxidized to the corresponding methylphenyl sulfoxide under the same conditions. | * |
dc.language | English | * |
dc.publisher | KOREAN CHEMICAL SOC | * |
dc.subject | mononuclear iron(II) complex | * |
dc.subject | macrocyclic ligand | * |
dc.subject | nonheme | * |
dc.subject | catalytic oxidation | * |
dc.title | Structure and properties of a nonheme pentacoordinate iron(II) complex with a macrocyclic triazapyridinophane ligand | * |
dc.type | Article | * |
dc.relation.issue | 8 | * |
dc.relation.volume | 27 | * |
dc.relation.index | SCI | * |
dc.relation.index | SCIE | * |
dc.relation.index | SCOPUS | * |
dc.relation.index | KCI | * |
dc.relation.startpage | 1140 | * |
dc.relation.lastpage | 1144 | * |
dc.relation.journaltitle | BULLETIN OF THE KOREAN CHEMICAL SOCIETY | * |
dc.identifier.wosid | WOS:000240394100008 | * |
dc.identifier.scopusid | 2-s2.0-33747841896 | * |
dc.author.google | You, Minyoung | * |
dc.author.google | Seo, Mi Sook | * |
dc.author.google | Kim, Kwan Mook | * |
dc.author.google | Nam, Wonwoo | * |
dc.author.google | Kim, Jinheung | * |
dc.contributor.scopusid | 남원우(7006569723) | * |
dc.contributor.scopusid | 김관묵(35484385500) | * |
dc.contributor.scopusid | 김진흥(8580015800) | * |
dc.date.modifydate | 20240116111857 | * |