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Temperature-dependent Raman spectroscopy in BaRuO3 systems

Title
Temperature-dependent Raman spectroscopy in BaRuO3 systems
Authors
Lee, YSNoh, TWPark, JHLee, KBCao, GCrow, JELee, MKEom, CBOh, EJYang, IS
Ewha Authors
양인상
SCOPUS Author ID
양인상scopus
Issue Date
2002
Journal Title
PHYSICAL REVIEW B
ISSN
1098-0121JCR Link
Citation
vol. 65, no. 23
Publisher
AMERICAN PHYSICAL SOC
Indexed
SCI; SCIE; SCOPUS WOS
Abstract
We investigated the temperature dependence of the Raman spectra of a nine-layer BaRuO3 single crystal and a four-layer BaRuO3 epitaxial film, which show pseudogap formations in their metallic states. From the polarized and depolarized spectra, the observed phonon modes are assigned properly according to the predictions of group theory analysis. In both compounds, with decreasing temperature, while A(1g) modes show a strong hardening, E-g (or E-2g) modes experience a softening or no significant shift. Their different temperature-dependent behaviors could be related to a direct Ru metal bonding through the face sharing of RuO6. It is also observed that another E-2g mode of the oxygen participating in the face sharing becomes split at low temperatures in the four-layer BaRuO3. And, the temperature dependence of the Raman continua between 250 and 600 cm(-1) is strongly correlated to the square of the plasma frequency. Our observations imply that there should be a structural instability in the face-shared structure, which could be closely related to the pseudogap formation of BaRuO3 systems.
DOI
10.1103/PhysRevB.65.235113
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자연과학대학 > 물리학전공 > Journal papers
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