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Anionic living polymerization of monomers with photo-electronic properties for control of polymeric nano architectures

Title
Anionic living polymerization of monomers with photo-electronic properties for control of polymeric nano architectures
Authors
Shin, YDCho, YSKim, JJLee, JSHan, SHWu, JW
Ewha Authors
우정원
SCOPUS Author ID
우정원scopus
Issue Date
2000
Journal Title
MOLECULAR CRYSTALS AND LIQUID CRYSTALS
ISSN
1542-1406JCR Link
Citation
vol. 349, pp. 9 - 14
Keywords
anionic living polymerizationblock copolymerphoto-electronic propertiesnano architecture
Publisher
TAYLOR & FRANCIS LTD
Indexed
SCI; SCIE; SCOPUS WOS scopus
Abstract
Block copolymers, 9-ethylcarbazolyl methacrylate (CzMA) with 3-nitro-9-ethylcarbazolyl methacrylate (NCzMA), and styrene with uptically functionalized isocyanates containing disperse red 1 (DRlNCO) and (s)-(-)-2-methylbutanol (MBI), were prepared by anionic polymerization for photo-electronic materials. The living condition of CzMA was found at -78 degreesC for 3 h with diethyl zinc and block copolymers of CzMA with NCzMA were synthesized successfully. The polymers show potential to be used as energy transfer materials in UV and PL spectra. Block copolymers of styrene with optically functionalized isocyanates were also synthesized with high yield and the polymers showed the large optical activity at 476 nm.
DOI
10.1080/10587250008024853
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자연과학대학 > 물리학전공 > Journal papers
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