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dc.contributor.author김영선.-
dc.creator김영선.-
dc.date.accessioned2016-08-26T10:08:30Z-
dc.date.available2016-08-26T10:08:30Z-
dc.date.issued1982-
dc.identifier.otherOAK-000000035560-
dc.identifier.urihttp://dspace.ewha.ac.kr/handle/2015.oak/201550-
dc.identifier.urihttp://dcollection.ewha.ac.kr/jsp/common/DcLoOrgPer.jsp?sItemId=000000035560-
dc.description.abstractA new alkylaminoalkoxyethoxydimethylsilane derivatives were synthesised by the reaction of dimethylethoxychlorosilane and alkylaminoalcohols. The used aminoalcohols were as follows: 1-amino-2-propanol, 1-dimethylamino-2-propanol, ℓ-2-amino-1-butanol, 2-amino-2-methyl-1-propanol, 3-amino-1-propanol and 3-dimethy-lamino-1-propanol. The products were easily seperated under reduced pressure. The products were (2-Amino-1-methyl-ethoxy) ethoxydimethylsilane, (2-N,N-Dimethylamino-1-methylethozy) ethoxydimethylsilane, (2-Amino-2,2-dimethylethoxy)ethoxydime-thylsilane, (3-Aminopropoxy)ethoxydimethylsilane and (3-N,N-Dimethylaminopropoxy) ethoxydimethylsilane.;Organohalosilane으로부터 aminoalkoxy기를 포함하는 새로운 aminoalkoxyorganosilane을 합성하였다. Me_(2)SiCl_(2)의 염소기 하나를 ethoxy기로 치환시켜 Me_(2)Si(OEt)Cl(Ⅰ)을 먼저 만든 뒤 이 화합물과 다음의 aminoalcohol 유도체들을 반응시켰다. 1-Amino-2-propanol, 1-dimethylamino-2-propanol, ℓ-2-amino-1-butanol 2-amino-2-methyl-1-propanol, 3-amino-1-propanol 및 3-dimethylamino-1-propanol을 반응시켰는데 생성된 화합물은 (2-amino-1-methylethoxy) ethoxydimethylsilane(Ⅱ), (2-N, N- dimethylamino-1-methylethoxy) ethoxydimethylsilane(Ⅲ), (2-amino-2-ethylethoxy) ethoxydimethylsilane(Ⅳ), (2-amino-2, 2-dimethylethoxy) ethoxydimethylsilane(Ⅴ), (3-aminopropoxy)-ethoxydimethylsilane(Ⅵ) 및 (3-N, N-dimethylaminopropoxy)-ethoxydimethylsilane(Ⅶ)이다. 합성된 화합물들을 감압 분별 증류하여 쉽게 분리하였으며, IR 및 NMR Spectra와 분자량 측정으로 확인하였다.-
dc.description.tableofcontents논문개요 = Ⅰ Ⅰ. 서론 = 1 Ⅱ. 실험 = 5 A. Dimethylethoxy chlorosilane의 합성 = 5 B. (2-Amino-1-methylethoxy)ethoxydimethylsilane의 합성 = 6 C. (2-N, N-Dimethylamino-1-methylethoxy)ethoxydimethylsilane의 합성 = 6 D. (2-Amino-2-ethylethoxy)ethoxydimethylsilane의 합성 = 7 E. (2-Amino-2, 2-dimethylethoxy)ethoxydimethylsilane의 합성 = 8 F. (3-Aminopropoxy)ethoxydimethylsilane의 합성 = 8 G. (3-N, N-Dimethylaminopropoxy)ethoxydimethylsilane의 합성 = 9 H. 시약의 건조 및 정제 = 9 1. Abolute ethyl ether의 건조 = 10 2. Ethyl Alcohol의 건조 = 10 Ⅲ. 결과 및 고찰 = 12 Ⅳ. 결론 = 27 참고문헌 = 37 영문초록 = 39-
dc.formatapplication/pdf-
dc.format.extent1147001 bytes-
dc.languagekor-
dc.publisher이화여자대학교 대학원-
dc.subjectOrganohalosilane-
dc.subjectaminoethanol-
dc.subject유도체-
dc.subject합성-
dc.titleOrganohalosilane과 aminoethanol 유도체와의 합성에 관한 연구-
dc.typeMaster's Thesis-
dc.title.translated(The) Synthesis of organohalosilane with aminoalcohol derivertives-
dc.format.pageiv, 39 p. : 삽도.-
dc.identifier.thesisdegreeMaster-
dc.identifier.major대학원 화학과-
dc.date.awarded1983. 2-
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