Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 이상기 | * |
dc.date.accessioned | 2023-01-18T16:32:52Z | - |
dc.date.available | 2023-01-18T16:32:52Z | - |
dc.date.issued | 2022 | * |
dc.identifier.issn | 1523-7060 | * |
dc.identifier.issn | 1523-7052 | * |
dc.identifier.other | OAK-32860 | * |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/263846 | - |
dc.description.abstract | The palladium-catalyzed divergent asymmetric synthesis of chiral spiro-furanindoline derivatives is described. The zwitterionic alkoxy pi-allyl Pd(II) intermediate, generated catalytically from vinyl ethylene carbonate (VEC), could undergo ligand-controlled enantio-and diastereoselective dipolar [3 + 2] spiroannulation with indole-based azadienes to afford the optically active spiro-furanindolines embedding an all-carbon quaternary stereocenter in high yields (up to 99%) with good to excellent stereoselectivities (up to 99% ee and up to >94:6 dr). | * |
dc.language | English | * |
dc.publisher | AMER CHEMICAL SOC | * |
dc.title | Divergent Asymmetric Synthesis of Chiral Spiroheterocycles through Pd-Catalyzed Enantio- and Diastereoselective [3+2] Spiroannulation | * |
dc.type | Article | * |
dc.relation.issue | 50 | * |
dc.relation.volume | 24 | * |
dc.relation.index | SCIE | * |
dc.relation.index | SCOPUS | * |
dc.relation.startpage | 9189 | * |
dc.relation.lastpage | 9193 | * |
dc.relation.journaltitle | ORGANIC LETTERS | * |
dc.identifier.doi | 10.1021/acs.orglett.2c03643 | * |
dc.identifier.wosid | WOS:000895977600001 | * |
dc.identifier.scopusid | 2-s2.0-85144105857 | * |
dc.author.google | Jeon, Hyun Ji | * |
dc.author.google | Park, Su Min | * |
dc.author.google | Lee, Yu Lim | * |
dc.author.google | Lee, Sang-gi | * |
dc.contributor.scopusid | 이상기(15082786300) | * |
dc.date.modifydate | 20240123104103 | * |