Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 김선희 | * |
dc.date.accessioned | 2021-11-10T16:31:14Z | - |
dc.date.available | 2021-11-10T16:31:14Z | - |
dc.date.issued | 2021 | * |
dc.identifier.issn | 0002-7863 | * |
dc.identifier.issn | 1520-5126 | * |
dc.identifier.other | OAK-30034 | * |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/259372 | - |
dc.description.abstract | Mononuclear Pd(I) species are putative intermediates in Pd-catalyzed reactions, but our knowledge about them is limited due to difficulties in accessing them. Herein, we report the isolation of a Pd(I) amido complex, [(BINAP)Pd(NHArTrip)] (BINAP = 2,2'-bis(diphenylphosphino)-1,1'-binaphthalene, Ar-Trip = 2,6-bis(2',4',6'-triisopropylphenyl)phenyl), from the reaction of (BINAP)PdCl2 with LiNHArTrip. This Pd(I) amido species has been characterized by X-ray crystallography, electron paramagnetic resonance, and multiedge Pd X-ray absorption spectroscopy. Theoretical study revealed that, while the three-electron-two-center pi-interaction between Pd and N in the Pd(I) complex imposes severe Pauli repulsion in its Pd-N bond, pronounced attractive interligand dispersion force aids its stabilization. In accord with its electronic features, reactions of homolytic Pd-N bond cleavage and deprotonation of primary amines are observed on the Pd(I) amido complex. | * |
dc.language | English | * |
dc.publisher | AMER CHEMICAL SOC | * |
dc.title | An Isolable Mononuclear Palladium(I) Amido Complex | * |
dc.type | Article | * |
dc.relation.issue | 28 | * |
dc.relation.volume | 143 | * |
dc.relation.index | SCIE | * |
dc.relation.index | SCOPUS | * |
dc.relation.startpage | 10751 | * |
dc.relation.lastpage | 10759 | * |
dc.relation.journaltitle | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | * |
dc.identifier.doi | 10.1021/jacs.1c04965 | * |
dc.identifier.wosid | WOS:000677544800036 | * |
dc.author.google | Liu, Jian | * |
dc.author.google | Bollmeyer, Melissa M. | * |
dc.author.google | Kim, Yujeong | * |
dc.author.google | Xiao, Dengmengfei | * |
dc.author.google | MacMillan, Samantha N. | * |
dc.author.google | Chen, Qi | * |
dc.author.google | Leng, Xuebing | * |
dc.author.google | Kim, Sun Hee | * |
dc.author.google | Zhao, Lili | * |
dc.author.google | Lancaster, Kyle M. | * |
dc.author.google | Deng, Liang | * |
dc.contributor.scopusid | 김선희(57205324645;57196230818) | * |
dc.date.modifydate | 20240130093611 | * |