Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 김원석 | * |
dc.date.accessioned | 2021-11-09T16:31:02Z | - |
dc.date.available | 2021-11-09T16:31:02Z | - |
dc.date.issued | 2021 | * |
dc.identifier.issn | 1523-7060 | * |
dc.identifier.issn | 1523-7052 | * |
dc.identifier.other | OAK-30266 | * |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/259214 | - |
dc.description.abstract | The design, synthesis, and validation of 3-aminobenzyne precursors induced by C-(sp(2))-to-N 1,3-aza-Brook rearrangement have been achieved, allowing access to diverse aniline derivatives. Through crossover experiments, we demonstrated the intramolecular mechanism of 1,3-C-to-N silyl transfer. To gain insight into the regioselectivity observed in the reactions, we performed density functional theory calculations. Finally, the method was applied to the synthesis of xylanigripones A in five linear steps in an overall yield of 30%. | * |
dc.language | English | * |
dc.publisher | AMER CHEMICAL SOC | * |
dc.title | 1,3-Aza-Brook Rearrangement of Aniline Derivatives: In Situ Generation of 3-Aminoaryne via 1,3-C-(sp(2))-to-N Silyl Migration | * |
dc.type | Article | * |
dc.relation.issue | 19 | * |
dc.relation.volume | 23 | * |
dc.relation.index | SCIE | * |
dc.relation.index | SCOPUS | * |
dc.relation.startpage | 7545 | * |
dc.relation.lastpage | 7549 | * |
dc.relation.journaltitle | ORGANIC LETTERS | * |
dc.identifier.doi | 10.1021/acs.orglett.1c02751 | * |
dc.identifier.wosid | WOS:000704710800044 | * |
dc.identifier.scopusid | 2-s2.0-85116579160 | * |
dc.author.google | Jeon, Young-Kyo | * |
dc.author.google | Kim, Won-Suk | * |
dc.contributor.scopusid | 김원석(57203484044) | * |
dc.date.modifydate | 20240220102223 | * |