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Acid Catalysis via Acid-Promoted Electron Transfer

Title
Acid Catalysis via Acid-Promoted Electron Transfer
Authors
Fukuzumi, ShunichiLee, Yong-MinNam, Wonwoo
Ewha Authors
남원우Shunichi Fukuzumi이용민
SCOPUS Author ID
남원우scopus; Shunichi Fukuzumiscopus; 이용민scopusscopus
Issue Date
2020
Journal Title
BULLETIN OF THE KOREAN CHEMICAL SOCIETY
ISSN
0253-2964JCR Link

1229-5949JCR Link
Citation
BULLETIN OF THE KOREAN CHEMICAL SOCIETY vol. 41, no. 12, pp. 1217 - 1232
Keywords
Metal&#8208oxygen complexesAcid catalysisAcid&#8208promoted electron transferProton&#8208coupled electron transferRedox reaction
Publisher
WILEY-V C H VERLAG GMBH
Indexed
SCIE; SCOPUS; KCI WOS
Document Type
Review
Abstract
This feature article focuses on acid catalysis in various redox reactions of not only organic compounds but also metal complexes, in particular metal-oxygen complexes via acid-promoted electron transfer (APET). On the other hand, proton-coupled electron transfer (PCET) has been extensively studied in relation with important biological PCET reactions such as O-2 reduction in respiration and water oxidation in photosynthesis. Because PCET is normally defined as simultaneous electron and proton transfer from the same substrate, acid-promoted electron transfer using external acids is called APET in this article. Various types of chemical transformations exhibiting acid catalysis via APET discussed in this article include C-C bond formation, C-H bond oxidation, aromatic hydroxylation, and oxygen atom transfer reactions such as sulfoxidation and epoxidation reactions.
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DOI
10.1002/bkcs.12124
Appears in Collections:
자연과학대학 > 화학·나노과학전공 > Journal papers
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