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dc.contributor.author남원우*
dc.contributor.author이용민*
dc.contributor.authorShunichi Fukuzumi*
dc.contributor.author서미숙*
dc.contributor.author김원석*
dc.date.accessioned2019-12-03T16:30:36Z-
dc.date.available2019-12-03T16:30:36Z-
dc.date.issued2019*
dc.identifier.issn1433-7851*
dc.identifier.otherOAK-26133*
dc.identifier.urihttps://dspace.ewha.ac.kr/handle/2015.oak/252339-
dc.description.abstractA mononuclear nonheme manganese(IV)–oxo complex binding the Ce4+ ion, [(dpaq)MnIV(O)]+–Ce4+ (1-Ce4+), was synthesized by reacting [(dpaq)MnIII(OH)]+ (2) with cerium ammonium nitrate (CAN). 1-Ce4+ was characterized using various spectroscopic techniques, such as UV/Vis, EPR, CSI-MS, resonance Raman, XANES, and EXAFS, showing an Mn−O bond distance of 1.69 Å with a resonance Raman band at 675 cm−1. Electron-transfer and oxygen atom transfer reactivities of 1-Ce4+ were found to be greater than those of MnIV(O) intermediates binding redox-inactive metal ions (1-Mn+). This study reports the first example of a redox-active Ce4+ ion-bound MnIV-oxo complex and its spectroscopic characterization and chemical properties. © 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim*
dc.languageEnglish*
dc.publisherWiley-VCH Verlag*
dc.subjectbiomimetic chemistry*
dc.subjectelectron transfer*
dc.subjecthigh-valent manganese–oxo*
dc.subjectoxygen atom transfer*
dc.subjectredox-active metal ions*
dc.titleA High-Valent Manganese(IV)–Oxo–Cerium(IV) Complex and Its Enhanced Oxidizing Reactivity*
dc.typeArticle*
dc.relation.issue45*
dc.relation.volume58*
dc.relation.indexSCIE*
dc.relation.indexSCOPUS*
dc.relation.startpage16124*
dc.relation.lastpage16129*
dc.relation.journaltitleAngewandte Chemie - International Edition*
dc.identifier.doi10.1002/anie.201910032*
dc.identifier.scopusid2-s2.0-85074026420*
dc.author.googleKarmalkar D.G.*
dc.author.googleSankaralingam M.*
dc.author.googleSeo M.S.*
dc.author.googleEzhov R.*
dc.author.googleLee Y.-M.*
dc.author.googlePushkar Y.N.*
dc.author.googleKim W.-S.*
dc.author.googleFukuzumi S.*
dc.author.googleNam W.*
dc.contributor.scopusid남원우(7006569723)-
dc.contributor.scopusidShunichi Fukuzumi(35430038100;57375583300)-
dc.contributor.scopusid서미숙(7101805112)-
dc.contributor.scopusid김원석(57203484044)-
dc.date.modifydate20221123095553*
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자연과학대학 > 화학·나노과학전공 > Journal papers
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