Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 남원우 | * |
dc.contributor.author | Shunichi Fukuzumi | * |
dc.date.accessioned | 2019-01-28T16:30:05Z | - |
dc.date.available | 2019-01-28T16:30:05Z | - |
dc.date.issued | 2019 | * |
dc.identifier.issn | 0002-7863 | * |
dc.identifier.other | OAK-24268 | * |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/248295 | - |
dc.description.abstract | A mononuclear nonheme iron(IV)-amido complex bearing a tetraamido macrocyclic ligand, [(TAML)FeIV(NHTs)]- (1), was synthesized via a hydrogen atom (H atom) abstraction reaction of an iron(V)-imido complex, [(TAML)FeV(NTs)]- (2), and fully characterized using various spectroscopies. We then investigated (1) the pKa of 1, (2) the reaction of 1 with a carbon-centered radical, and (3) the H atom abstraction reaction of 1. To the best of our knowledge, the present study reports for the first time the synthesis and chemical properties/reactions of a high-valent iron(IV)-amido complex. © 2018 American Chemical Society. | * |
dc.language | English | * |
dc.publisher | American Chemical Society | * |
dc.title | A Mononuclear Nonheme Iron(IV)-Amido Complex Relevant for the Compound II Chemistry of Cytochrome P450 | * |
dc.type | Article | * |
dc.relation.issue | 1 | * |
dc.relation.volume | 141 | * |
dc.relation.index | SCIE | * |
dc.relation.index | SCOPUS | * |
dc.relation.startpage | 80 | * |
dc.relation.lastpage | 83 | * |
dc.relation.journaltitle | Journal of the American Chemical Society | * |
dc.identifier.doi | 10.1021/jacs.8b11045 | * |
dc.identifier.wosid | WOS:000455561800015 | * |
dc.identifier.scopusid | 2-s2.0-85059848067 | * |
dc.author.google | Lu X. | * |
dc.author.google | Li X.-X. | * |
dc.author.google | Seo M.S. | * |
dc.author.google | Lee Y.-M. | * |
dc.author.google | Clémancey M. | * |
dc.author.google | Maldivi P. | * |
dc.author.google | Latour J.-M. | * |
dc.author.google | Sarangi R. | * |
dc.author.google | Fukuzumi S. | * |
dc.author.google | Nam W. | * |
dc.contributor.scopusid | 남원우(7006569723) | * |
dc.contributor.scopusid | Shunichi Fukuzumi(35430038100;58409757400) | * |
dc.date.modifydate | 20240401081001 | * |