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A Mononuclear Nonheme Iron(IV)-Amido Complex Relevant for the Compound II Chemistry of Cytochrome P450

Title
A Mononuclear Nonheme Iron(IV)-Amido Complex Relevant for the Compound II Chemistry of Cytochrome P450
Authors
Lu X.Li X.-X.Seo M.S.Lee Y.-M.Clémancey M.Maldivi P.Latour J.-M.Sarangi R.Fukuzumi S.Nam W.
Ewha Authors
남원우Shunichi Fukuzumi
SCOPUS Author ID
남원우scopus; Shunichi Fukuzumiscopus
Issue Date
2019
Journal Title
Journal of the American Chemical Society
ISSN
0002-7863JCR Link
Citation
Journal of the American Chemical Society vol. 141, no. 1, pp. 80 - 83
Publisher
American Chemical Society
Indexed
SCIE; SCOPUS WOS scopus
Document Type
Article
Abstract
A mononuclear nonheme iron(IV)-amido complex bearing a tetraamido macrocyclic ligand, [(TAML)FeIV(NHTs)]- (1), was synthesized via a hydrogen atom (H atom) abstraction reaction of an iron(V)-imido complex, [(TAML)FeV(NTs)]- (2), and fully characterized using various spectroscopies. We then investigated (1) the pKa of 1, (2) the reaction of 1 with a carbon-centered radical, and (3) the H atom abstraction reaction of 1. To the best of our knowledge, the present study reports for the first time the synthesis and chemical properties/reactions of a high-valent iron(IV)-amido complex. © 2018 American Chemical Society.
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DOI
10.1021/jacs.8b11045
Appears in Collections:
자연과학대학 > 화학·나노과학전공 > Journal papers
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