DSpace at EWHA: Stereochemistry of metal tetramethylcyclam complexes directed by an unexpected anion effect

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DSpace at EWHA자연과학대학 화학·나노과학전공 Journal papers

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DC Field	Value	Language
dc.contributor.author	김선희	*
dc.date.accessioned	2018-12-07T16:30:21Z	-
dc.date.available	2018-12-07T16:30:21Z	-
dc.date.issued	2017	*
dc.identifier.issn	1477-9226	*
dc.identifier.other	OAK-21492	*
dc.identifier.uri	https://dspace.ewha.ac.kr/handle/2015.oak/247284	-
dc.description.abstract	Metal(TMC) complexes (TMC = tetramethylcyclam) exclusively form trans-I diastereoisomers; thus, little is known about the trans-III isomers. Herein, we report a new method to prepare the trans-III-[Cu(TMC)]2+ complex via an anion effect. Our crystallographic, spectroscopic, and computational analyses validated that [Cu(TMC)](NO3)2 produced the trans-III complex, different from the trans-I structure of [Cu(TMC)](ClO4)2. © 2017 The Royal Society of Chemistry.	*
dc.description.sponsorship	Korea Institute of Science and Technology Information	*
dc.language	English	*
dc.publisher	Royal Society of Chemistry	*
dc.title	Stereochemistry of metal tetramethylcyclam complexes directed by an unexpected anion effect	*
dc.type	Article	*
dc.relation.issue	39	*
dc.relation.volume	46	*
dc.relation.index	SCIE	*
dc.relation.index	SCOPUS	*
dc.relation.startpage	13166	*
dc.relation.lastpage	13170	*
dc.relation.journaltitle	Dalton Transactions	*
dc.identifier.doi	10.1039/c7dt01489a	*
dc.identifier.wosid	WOS:000412765000002	*
dc.identifier.scopusid	2-s2.0-85031032726	*
dc.author.google	Derrick J.S.	*
dc.author.google	Kim Y.	*
dc.author.google	Tak H.	*
dc.author.google	Park K.	*
dc.author.google	Cho J.	*
dc.author.google	Kim S.H.	*
dc.author.google	Lim M.H.	*
dc.contributor.scopusid	김선희(57205324645;57196230818)	*
dc.date.modifydate	20250301081000	*