Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | 남원우 | * |
dc.contributor.author | 이용민 | * |
dc.contributor.author | Shunichi Fukuzumi | * |
dc.date.accessioned | 2018-11-21T16:30:25Z | - |
dc.date.available | 2018-11-21T16:30:25Z | - |
dc.date.issued | 2018 | * |
dc.identifier.issn | 0947-6539 | * |
dc.identifier.other | OAK-22353 | * |
dc.identifier.uri | https://dspace.ewha.ac.kr/handle/2015.oak/246738 | - |
dc.description.abstract | Hydrogen peroxide, which is a green oxidant and fuel, is produced by a two-electron/two-proton reduction of dioxygen, two-electron/two-proton oxidation of water, or a combination of four-electron/four-proton or/and two-electron/two-proton oxidation of water and two-electron/two-proton reduction of dioxygen. There are many reports on electrocatalysts for selective two-electron/two-proton reduction of dioxygen to produce hydrogen peroxide instead of four-electron/four-proton reduction of dioxygen to produce water. As compared with the two-electron/two-proton reduction of dioxygen to produce hydrogen peroxide, fewer catalysts are known for the selective two-electron/two-proton oxidation of water to produce hydrogen peroxide instead of four-electron/four-proton oxidation of water to evolve dioxygen. Thus, solar-driven production of hydrogen peroxide mainly consists of the catalytic four-electron/four-proton oxidation of water and the catalytic two-electron/two-proton reduction of dioxygen. The overall reaction is the solar-driven oxidation of water by dioxygen to produce hydrogen peroxide. Either or both the four-electron/four-proton or/and the two-electron/two-proton oxidation of water and the two-electron/two-proton reduction of dioxygen requires photocatalysts. The yield of hydrogen peroxide is improved when the compartment for the photocatalytic four-electron/four-proton or/and two-electron/two-proton oxidation of water is separated from that for the catalytic two-electron/two-proton reduction of dioxygen using a two-compartment cell separated by a membrane. The overall solar-driven oxidation of water by dioxygen, which is the greenest oxidant, to produce hydrogen peroxide can be combined with catalytic oxidation of various substrates by hydrogen peroxide. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim | * |
dc.description.sponsorship | Japan Science and Technology Agency | * |
dc.language | English | * |
dc.publisher | Wiley-VCH Verlag | * |
dc.subject | hydrogen peroxide | * |
dc.subject | photocatalyst | * |
dc.subject | two-electron oxidation of water | * |
dc.subject | two-electron reduction of dioxygen | * |
dc.subject | water oxidation catalyst | * |
dc.title | Solar-Driven Production of Hydrogen Peroxide from Water and Dioxygen | * |
dc.type | Review | * |
dc.relation.issue | 20 | * |
dc.relation.volume | 24 | * |
dc.relation.index | SCIE | * |
dc.relation.index | SCOPUS | * |
dc.relation.startpage | 5016 | * |
dc.relation.lastpage | 5031 | * |
dc.relation.journaltitle | Chemistry - A European Journal | * |
dc.identifier.doi | 10.1002/chem.201704512 | * |
dc.identifier.wosid | WOS:000429703700002 | * |
dc.identifier.scopusid | 2-s2.0-85041577119 | * |
dc.author.google | Fukuzumi S. | * |
dc.author.google | Lee Y.-M. | * |
dc.author.google | Nam W. | * |
dc.contributor.scopusid | 남원우(7006569723) | * |
dc.contributor.scopusid | Shunichi Fukuzumi(35430038100;58409757400) | * |
dc.contributor.scopusid | 이용민(36546331100;35233855500;57192113229) | * |
dc.date.modifydate | 20240426135715 | * |