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자연과학대학
화학·나노과학전공
Journal papers
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The detoxin complex.-A naturally occurring safener
Title
The detoxin complex.-A naturally occurring safener
Authors
Li W.-R.
;
Hant S.-Y.
;
Joullie M.M.
Ewha Authors
한소엽
SCOPUS Author ID
한소엽
Issue Date
1993
Journal Title
Heterocycles
ISSN
0385-5414
Citation
Heterocycles vol. 36, no. 2, pp. 359 - 388
Indexed
SCI; SCIE; SCOPUS
Document Type
Article
Abstract
The detoxin complex is a group of depsipeptide metabolites produced by the organism Streptomyces caespitosus var. detoxicus 7072 GC1 as well as other strains of Streptomyces. The complex is the first isolated natural product which displays a unique detoxification effect in plant and animal cells as its biological activity. The structural investigations carried out to elucidate the structures of the congeners and the stereochemistry of the stereogenic centers are described. Structure-activity relationships are discussed. The different synthetic approaches to the parent amino acid, (-)detoxinine, are compared. The syntheses of detoxins (-)-B1, (-)-B3, (-)-D1, and(+)-valyldetoxinine are described. © 1993.
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