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End-capped silole dendrimers on a carbosilane periphery: Potential electroluminescent materials
- Title
- End-capped silole dendrimers on a carbosilane periphery: Potential electroluminescent materials
- Authors
- Son H.-J.; Han W.-S.; Kim H.; Kim C.; Ko J.; Lee C.; Kang S.O.
- Ewha Authors
- 이종목
- SCOPUS Author ID
- 이종목
- Issue Date
- 2006
- Journal Title
- Organometallics
- ISSN
- 0276-7333
- Citation
- Organometallics vol. 25, no. 3, pp. 766 - 774
- Indexed
- SCI; SCIE; SCOPUS
- Document Type
- Article
- Abstract
- The divergent synthesis of end-capped silole dendrimers Gn-2 n+1Silole (n = 1-4) using 2,4,6,8tetramethyl-2,4,6,8- tetravinylcyclotetrasiloxane [Me(CH2=CH)SiO]4 as a core molecule and allyl alcohol/ dichloromethylsilane as a building block is described in this paper. The reaction of the dichloride functionalities of the carbosiloxane dendrimers Gn-2n+2Cl (n = 1-4) with the 1,4-diphenylbutadiene1,4-dianions (1) provided an effective route for the attachment of silole functionalities to a dendritic periphery. In addition, dendritic siloles GBn-2nSilole (n = 1-3) based on phenylethynylmethylsilane (PhC=C)2Me2Si as cores were synthesized. The building blocks of the dendrimers consisted of double bonds (-PhC=CHMeSi-) in the inner shell and silole groups on the outermost periphery. The generational limit of the dendrimer for the two-branching type core molecule was found to have eight silole groups for the third generation. All of the dendrimers were characterized by 1H and 13C{1H} NMR, UV spectroscopy, cyclic votammetry (CV), and size exclusion chromatography (SEC). Using this methodology, a series of silole-containing dendrimer systems showing green to greenish-blue fluorescence were synthesized. © 2006 American Chemical Society.
- DOI
- 10.1021/om050991v
- Appears in Collections:
- 자연과학대학 > 화학·나노과학전공 > Journal papers
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