Tuning the intermolecular dative interactions by altering the ligand planarity and counter cations in vanadyl(IV) complexes

Abstract

A vanadyl(IV) complex, K2V(O)(dtoym)2, forms polymeric interactions via intermolecular dative bonds; the intermolecular dative interaction is tuned by changes of the ligand planarity and counter cations of the vanadyl complex. © The Royal Society of Chemistry 2005.