Angewandte Chemie - International Edition vol. 43, no. 18, pp. 2417 - 2420
Indexed
SCI; SCIE; SCOPUS
Document Type
Article
Abstract
Rates of exchange: Evidence that non-heme oxoiron(IV) complexes exchange their oxygen atoms with H218O was obtained for the first time, by monitoring electrospray ionization mass spectral changes of the oxoiron(IV) species. The oxygen-atom exchange depended markedly on the amounts of H218O present and reaction temperatures but not on the presence of trans axial ligand (see scheme).