DSpace at EWHA: A Mononuclear Nonheme Iron(V)-Imido Complex

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DC Field	Value	Language
dc.contributor.author	남원우	*
dc.contributor.author	이용민	*
dc.date.accessioned	2017-10-27T11:45:27Z	-
dc.date.available	2017-10-27T11:45:27Z	-
dc.date.issued	2017	*
dc.identifier.issn	0002-7863	*
dc.identifier.other	OAK-20977	*
dc.identifier.uri	https://dspace.ewha.ac.kr/handle/2015.oak/237208	-
dc.description.abstract	Mononuclear nonheme iron(V)-oxo complexes have been reported previously. Herein, we report the first example of a mononuclear nonheme iron(V)-imido complex bearing a tetraamido macrocyclic ligand (TAML), [(TAML)Fe-V(NTs)](-) (1). The spectroscopic characterization of 1 revealed an S = 1/2 Fe(V) oxidation state, an Fe-N bond length of 1.65(4) angstrom, and an Fe-N vibration at 817 cm(-1). The reactivity of 1 was demonstrated in C-H bond functionalization and nitrene transfer reactions.	*
dc.language	English	*
dc.publisher	AMER CHEMICAL SOC	*
dc.title	A Mononuclear Nonheme Iron(V)-Imido Complex	*
dc.type	Article	*
dc.relation.issue	26	*
dc.relation.volume	139	*
dc.relation.index	SCIE	*
dc.relation.index	SCOPUS	*
dc.relation.startpage	8800	*
dc.relation.lastpage	8803	*
dc.relation.journaltitle	JOURNAL OF THE AMERICAN CHEMICAL SOCIETY	*
dc.identifier.doi	10.1021/jacs.7b04695	*
dc.identifier.wosid	WOS:000405158900006	*
dc.identifier.scopusid	2-s2.0-85022056323	*
dc.author.google	Hong, Seungwoo	*
dc.author.google	Sutherlin, Kyle D.	*
dc.author.google	Vardhaman, Anil Kumar	*
dc.author.google	Yan, James J.	*
dc.author.google	Park, Sora	*
dc.author.google	Lee, Yong-Min	*
dc.author.google	Jang, Soojeong	*
dc.author.google	Lu, Xiaoyan	*
dc.author.google	Ohta, Takehiro	*
dc.author.google	Ogura, Takashi	*
dc.author.google	Solomon, Edward I.	*
dc.author.google	Nam, Wonwoo	*
dc.contributor.scopusid	남원우(7006569723)	*
dc.date.modifydate	20240405124502	*