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Synthesis, structure and luminescence properties of new chalcogenide octahedral rhenium cluster complexes with 4-aminopyridine [{Re(6)Q(8)}(4-NH2-py)(6)](2+)
- Title
- Synthesis, structure and luminescence properties of new chalcogenide octahedral rhenium cluster complexes with 4-aminopyridine [{Re(6)Q(8)}(4-NH2-py)(6)](2+)
- Authors
- Ivanov, Anton A.; Khlestkin, Vadim K.; Brylev, Konstantin A.; Eltsov, Ilia V.; Smolentsev, Anton I.; Mironov, Yuri V.; Shestopalov, Michael A.
- Ewha Authors
- Mironov Yuri Vladimorovich
- Issue Date
- 2016
- Journal Title
- JOURNAL OF COORDINATION CHEMISTRY
- ISSN
- 0095-8972
1029-0389
- Citation
- JOURNAL OF COORDINATION CHEMISTRY vol. 69, no. 5, pp. 841 - 850
- Keywords
- Rhenium cluster; 4-Aminopyridine; Luminescence; Crystal structure
- Publisher
- TAYLOR &
FRANCIS LTD
- Indexed
- SCI; SCIE; SCOPUS
- Document Type
- Article
- Abstract
- Two new cationic octahedral rhenium cluster complexes [{Re(6)Q(8)}(4-NH2-py)(6)](2+) (Q = S, Se; 4-NH2-py = 4-aminopyridine) were synthesized by reactions of cesium salts of cluster anions [{Re(6)Q(8)}Br-6](4-/3-) with molten 4-aminopyridine. Both complexes were separated as salts with Br- as counterions and the structure of [{Re6S8}(4-NH(2)(-)py)(6)]Br-2 center dot 6DMF was revealed by X-ray single-crystal diffraction analysis. The compounds were characterized by elemental analysis, energy dispersive X-ray, IR, NMR, and luminescence spectroscopies. [GRAPHICS] .
- DOI
- 10.1080/00958972.2016.1142537
- Appears in Collections:
- 연구기관 > 지능형나노바이오소재연구센터 > Journal papers
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